A few immediately come to mind: Global from Macross, Bright from Gundam, Kotarou from Gaogaigar. But, for me, Captain Harlock stands undisputed at the top of the pile.
Pretty much no other person could manage the crew of the Arcadia. They are a bunch of outlaws who serve the ship only because Harlock is at the helm. He is always ready with the next move or plan, and his quiet confidence inspires awe, respect and devotion in his crew (as well as his adversaries). He knows when to give an encouraging word and when to slap the taste out of someone's mouth. Harlock is driven but not obsessive, determined to achieve but not at the cost of persons he cares about.
The man can drink anyone under the table. He's not trying to get wasted or anything, he just often downs a glass of wine while, say, mapping out strategy or interrogating a prisoner. The amount of red wine the guy imbibes throughout the series is staggering, yet he never shows one sign of even being tipsy.
Oh and he can duel very well.
